Dielectric and IR spectroscopy
|
THz science and technology
|
Light and neutron scattering
|
Theory and simulations |
Solid-state materials science
|
Liquid crystals |
About us
Main activities of Department of Dielectrics cover experimental and theoretical investigations of high-permittivity insulators like liquid crystals, ferroelectrics, multiferroics, piezoelectrics, semiconductor nanostructures, and low-loss materials.
- Dielectric and IR spectroscopy
- THz science and technology
- Light and neutron scattering
- Theory and simulations
- Solid-state materials science
- Liquid crystals
The most significant fresh scientific results of our deparment are listed in the section Highlights.
First book on functional ferroelectric domain walls
P. Ondrejkovic, P. Marton, V. Stepkova and J. Hlinka contributed by the chapter: “Fundamental properties of ferroelectric domain walls from Ginzburg-Landau models” to a new book titled “Domain Walls: From Fundamental Properties to Nanotechnology Concepts” published by Oxford University Press.
The book covers:
- Comprehensive coverage beyond scientific reviews
- Information is accessible for non-specialists and newcomers
- Explores ideas for future research within the area
Description:
Technological evolution and revolution are both driven by the discovery of new functionalities, new materials and the design of yet smaller, faster, and more energy-efficient components. Progress is being made at a breathtaking pace, stimulated by the rapidly growing demand for more powerful and readily available information technology. High-speed internet and data-streaming, home automation, tablets and smartphones are now "necessities" for our everyday lives. Consumer expectations for progressively more data storage and exchange appear to be insatiable.
Oxide electronics is a promising and relatively new field that has the potential to trigger major advances in information technology. Oxide interfaces are particularly intriguing. Here, low local symmetry combined with an increased susceptibility to external fields leads to unusual physical properties distinct from those of the homogeneous bulk.
In this context, ferroic domain walls have attracted recent attention as a completely new type of oxide interface. In addition to their functional properties, such walls are spatially mobile and can be created, moved, and erased on demand. This unique degree of flexibility enables domain walls to take an active role in future devices and hold a great potential as multifunctional 2D systems for nanoelectronics. With domain walls as reconfigurable electronic 2D components, a new generation of adaptive nano-technology and flexible circuitry becomes possible, that can be altered and upgraded throughout the lifetime of the device. Thus, what started out as fundamental research, at the limit of accessibility, is finally maturing into a promising concept for next-generation technology.
Popular cartoon video about smart materials
Teťana Ostapčuk contributed as a scientific guarantor to a popular cartoon video about piezoelectric materials, shape memory alloys, photo-, thermo-, electro- and magnetochromic materials and their applications (in Czech only).
The video comes from the series of Undistorted Science.
Snapshot form the video about Smart materials (YouTube).
Karel Tesař among winners of the Materials Today Cover Competition 2019
Karel's photo taken by an electron microscope succeeded in the Materials Today Cover Competition 2019. So-called 'Uncovered article' about biodegradable magnesium implants, closely related to the winning photo, has been recently published in Materials Today.
The image of the winners will be featured on the cover of an issue of the journal. The authors have also the privilege to write an article to uncover a story behind their winning photos. Karel Tesař and his collaborator Karel Balík (Institute of Rock Structure and Mechanics, Czech Academy of Sciences) contributed by a short article about the state-of-art research on biodegradable implants: Nucleation of corrosion products on H2 bubbles: A problem for biodegradable magnesium implants?. An interview with Karel Tesař is available on the website of the Institute of Physics of the Czech Academy of Sciences.
Winning photograph - hydroxyapatite as a product of the degradation of magnesium wire in synthetic cell culture medium. The hollow shape is a result of hydrogen generation and nucleation of corrosion products on the gas/liquid interfacea.
New material for 5G mobile networks
Epitaxial strained thin films of (SrTiO3)n-1(BaTiO3)1SrO were found to be a promising new material for mobile network of the 5th generation [Nature Mater. 19, 176 (2020)].
Epitaxial strained thin films of (SrTiO3)n-1(BaTiO3)1SrO were grown on DyScO3 substrates using molecular beam epitaxy [1]. The best microwave dielectric properties were discovered in samples with n= 6. Permittivity exhibits huge tuning using electric field and microwave dielectric loss is anomalously low. Unique properties were confirmed using first-principles calculations and by experimental observation of the soft mode behavior in THz region. These films are ideal for components in 5G networks.
Collaborating institutions: Prof. D.G. Schlom from the Cornell University and other American and German institutions.
Figure: Schema of crystal structures of investigated (SrTiO3)n-1(BaTiO3)1SrO films and their view in scanning transmission electron microscope. Yellow octahedra depict TiO6 layers, green and red points mark atoms of Sr and Ba.
[1] N.M. Dawley, E.J.Marksz, A.M. Hagerstrom, G.H. Olsen, M.E. Holtz, V. Goian, C. Kadlec, J. Zhang, X. Lu, J.A. Drisko, R. Uecker, S. Ganschow, C.J. Long, J.C. Booth, S. Kamba, C.J. Fennie, D.A. Muller, N.D. Orloff, D.G. Schlomk, Targeted chemical pressure yields tuneable millimetre-wave dielectric, Nature Mater. 19, 176 (2020).
(show less)
Organic nanotubes created from mesogenic lactic acid derivatives
We found a facile route how to prepare nanotubes from rod-like mesogens dissolved in typical organic solvents. For selected types of chiral rod-like molecules, both enantiomers as well as the racemic mixtures, the nanotubes are formed by slow evaporation from a solution, regardless the solvent, concentration or deposition type. Obtained supramolecular assemblies were studied using various experimental techniques and nanotubes of 50-60 nm diameter described. We proposed rolling-up mechanism related to the surface tension difference at the opposite layer surfaces.
Figure: In the background AFM picture shows nanotubes, the diameter of observed nanotubes is 50-60 nm. A scrolling-up mechanism of crystalline molecular layers was proposed based on difference between the surface tension at the opposite surfaces.
[1] V. Novotná, V. Hamplová, L. Lejček, D. Pociecha, M. Cigl, L. Fekete, M. Glogarová, L. Bednárová, P. Majewski, E. Gorecka. Organic nanotubes created from mesogenic derivatives Nanoscale Adv. 1, 2835(2019).
(show less)
Mesoscopic polarization dynamics and two ferroelectric sublattices
in the uniaxial tetragonal tungsten bronze (Srx Ba1−x)Nb2O6
The high-frequency dielectric behavior of uniaxial tungsten-bronze strontium barium niobate crystals with various Sr/Ba ratios have been studied in order to thoroughly understand the evolution of the relaxation dynamics across the ferroelectric phase transition. We showed that the dielectric response along the polar axis consists of three relaxations corresponding to polarization mechanisms related to several correlation lengths of mesoscopic order and that they are closly associated with two different ferroelectric subsystems.in the structure [1].
The archetypical uniaxial tungsten-bronze (Sr
Fig. 1: (a) Structure of SBN in the ab plane [dashed red lines mark the perovskite subunit in lighter-coloured octahedra Nb(2)O6, linking oxygen octahedra Nb(1)O6 are shown in blue colour]. (b) Contribution to the spontaneous polarization of Nb(1) and Nb(2).
The high-frequency dielectric behaviour of SBN (from 104 to 1013 Hz), investigated in a broad temperature interval for compositions from pure ferroelectric (SBN-35) to relaxor (SBN-81) ones, revealed that the dielectric response along the polar axis consists of three relaxations related to polarization mechanisms with various correlation lengths of mesoscopic order [1].. All of them show dissimilar behaviours with temperature, pointing out to their distinct nature [Fig. 2]. A temperature-dependent central mode at THz frequencies and a relaxation above 10 GHz are accompanied by the slowing down of a relaxation in the MHz range. This complex response reveals coexistence of displacive and order-disorder scenarios in this family.
Fig. 2: (a) Temperature dependences of the frequencies of the main excitations found in SBN crystals. (b) Contribution to the permittivity of the main excitations in SBN crystals. The shaded regions refer to extended error regions found for νGHz and ΔεGHz.
[1] E. Buixaderas, M. Kempa, Š. Svirskas, C. Kadlec, V. Bovtun, M. Savinov, M. Paściak, and J. Dec, Dynamics of mesoscopic polarization in the uniaxial tetragonal tungsten bronze (Sr
(show less)
Changes in spin and lattice dynamics induced by magnetic and structural phase transitions in multiferroic SrMn7O12
Upon cooling, SrMn7O12 undergoes a series of structural and magnetic phase transitions from cubic to rhombohedral symmetry, and to an incommensurately modulated crystal structure, which is connected with charge and orbital ordering of the Mn cations. We report IR, THz, and Raman spectra of SrMn7O12 ceramics reflecting corresponding changes in the phonon selection rules, including new phonons appearing in spin-order-induced ferroelectric phases [1].
The observed phonon activities are compared with the predictions from the factor-group analysis. In the high-temperature phase, more phonons are observed than the number predicted for the cubic symmetry. This is explained by the presence of rhombohedral clusters in the cubic phase. The strongest variations occur in the THz spectra near the two magnetic phase transitions, at TN1 = 87 K and TN2 = 63 K. These activate new modes in the spectra, with resonance frequencies and intensities changing with temperature and magnetic field. Below TN2, we observed a transfer of oscillator strengths from low-frequency phonons to these excitations, which we assign to electromagnons.
Figure: (a) Temperature dependence of the low-frequency excitations observed in THz and IR spectra of SrMn7O12. The open symbols correspond to spin excitations or phonons activated by breaking of the inversion center, whereas the remaining phonons are marked by solid symbols. (b) Rhombohedral quadruple perovskite crystal structure of SrMn7O12.
[1] S. Kamba, V. Goian, F. Kadlec, D. Nuzhnyy, C. Kadlec, J. Vít, F. Borodavka, I. S. Glazkova, A. A. Belik, Changes in spin and lattice dynamics induced by magnetic and structural phase transitions in multiferroic SrMn7O12, Phys. Rev. B 99, 184108 (2019).
(show less)
Raman scattering yields cubic crystal grain orientation
The anisotropy of Raman scattering was applied to determine the orientation of individual microcrystal grains, as small as a few µm, of GaV4S8 polycrystalline compound. This was possible by measuring polarised Raman spectra as a function of rotation of the sample along the laser direction. On comparing the resulting set of spectra with a computer simulation for particular symmetries, the orientation of the crystal grains could of the determined with good precision.
Figure:
Grain morphology of the investigated GaV4S8 ceramics.
(a) Scanning electron microscope image of an area of interest with sample coordinate system as an inset;
(b) Inverse pole figure map from EBSD analysis of the area in (a);
(c) positions of four grains chosen for detailed Raman measurements,
indicated projections of elementary cubic cells clarify their crystallographic orientation;
(d) unit triangle with the colour code of the inverse pole figure map;
(e) surface normals of the chosen grains;
(f) Parallel-polarised Raman scattering intensity ratios detected from the four grains,
which allows determination of their crystallographic orientation independent of the EBSD analysis.
Data shows intensity ratio at selected frequencies as a function of the angle ϕ
between the polariser and the reference direction on the sample surface.
K. Tesar, I. Gregora, P. Beresova, P. Vanek, P. Ondrejkovic, and J. Hlinka, Raman scattering yields cubic crystal grain orientation, Scientific Reports 9, 9385 (2019).
(show less)
Soft mode driven local ferroelectric transition in lead-based relaxors
Analysis of IR and THz spectra using Bruggeman effective medium approach revealed that the mesoscopic structure of Pb(Mg1/3Nb2/3)O3 and Pb(Mg1/3Ta2/3)O3 consists of dynamic randomly oriented uniaxially anisotropic polar nanoregions with harder transverse optical polar modes in the direction along the local dipoles [1,2].
The lowest-frequency phonon of the E symmetry polarized perpendicular to the local dipole moments undergoes softening towards T* ≈ 400 K, which brings evidence about a local structural phase transition. This softening is also responsible for previously observed high temperature dependence of permittivity, which follows the Curie-Weiss law.
Figure: (a) Temperature dependence of the overdamped E component of the soft mode in PMN, PMT and PMN-PT characterized by frequency of the peak in dielectric loss. (b) Temperature dependence of the reciprocal static permittivity (perpendicular to local polarization in nanodomains) obtained from the fits of IR and THz spectra.
[1] D. Nuzhnyy, J. Petzelt, V. Bovtun, S. Kamba, J. Hlinka, Infrared, terahertz, and microwave spectroscopy of the soft and central modes in Pb(Mg1/3Nb2/3)O3, Phys. Rev. B 96, 174113 (2017).
[2] D. Nuzhnyy et al., Soft mode driven local ferroelectric transition in lead-based relaxors, Appl. Phys. Lett. 114, 182901 (2019).
(show less)
Degenerate (identity) chemical reactions in ferroelastic crystals
The work points to reconsideration of degenerate chemical reactions because of the chemical reactions which take place in a solid phase where the orientation of the substituting molecules is maintained. The work points to the examples of a ferroelastic switching which is accompanied by braking and reestablisment of chemical bonds. The article suggests that the definition of the degenerate chemical reactions might distinguish the reactions where the truly identical molecules are formed from those ones where the resulting molecules are enantiomers or enatiomorphs in case of domains.
Figure: (a) The prototypic (paraelastic) phase with a pair of equivalent atoms related by the symmetry operation g with the related symmetry element go. (b) The ferroelastic domain pair is related by the suppressed (lost) symmetry element gs. There is a pseudosymmetry element gr within each domain state which is a remnant of the suppressed (lost) symmetry element go.
J. Fábry, Degenerate (identity) chemical reactions in ferroelastic crystals, Acta Cryst. B75, 287(2019).
(show less)
Targeted chemical pressure yields tuneable millimetre-wave dielectric
Nature Materials 19, 176 (2020).
Temperature-independent giant dielectric response in transitional BaTiO3 thin films
Appl. Phys. Rev. 7, 011402 (2020).
Structural, magnetic, and spin dynamical properties of the polar antiferromagnets Ni3-xCoxTeO6(x=1,2)
Phys. Rev. B 101, 014429 (2020).
Microstructure and micromechanical properties of GaV4S8 ceramics prepared by single-step solid state synthesis
Ceram. Int. 46, 7045 (2020).
New perspectives for heavily boron-doped diamond Raman spectrum analysis
Carbon
Raman spectra of fine-grained materials from first principles
npj Computational Materials 121, 1 (2020).
Terahertz Spectroscopy of Nanomaterials: a Close Look at Charge-Carrier Transport
Adv. Opt. Mater. 8, 1900623 (2020).